Scientific journal
Bulletin of Higher Educational Institutions
North Caucasus region

TECHNICAL SCIENCES


UNIV. NEWS. NORTH-CAUCAS. REG. TECHNICAL SCIENCES SERIES. 2016; 1: 99-105

 

http://dx.doi.org/10.17213/0321-2653-2016-1-99-105

 

THE POSSIBILITY OF PREDICTING THE MASS RATE OF ANODIC DISSOLUTION OF A MATERIAL FERROSILICON ANODE GROUNDING

T.V. Lipkina, S.A. Pozhidayeva, Yu.N. Nikolaeva, M.A. Gavrilova

Lipkina Tatyana Valeryevna – Candidate of Technical Sciences, assistant professor, department «Ecology, Technologies of Electrochemical Productions and Resource-saving», Platov South-Russian State Polytechnic University (NPI). Novocherkassk, Russia. Ph. (8635)2-55-335.

Pozhidayeva Svetlana Aleksandrovna – Candidate of Technical Sciences, assistant professor, department «Chemical Technology of High-molecular Connections, Organic, Physical and Colloidal Chemistry», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia. Ph. (8635)2-55-339.

Nikolaeva Yuliya Nikolaevna – post-graduate student, department «Ecology, Technologies of Electrochemical Productions and Resource-saving», Platov South-Russian State Polytechnic University (NPI), Novocherkassk, Russia. Ph. (8635)2-55-335. E-mail: yuliya_nik-91@mail.ru

Gavrilova Mariya Aleksandrovna – student, Platov South-Russian State Polytechnic University (NPI). Ph. (8635)2-55-335. E-mail: mariya_gavrilova_92@mail.ru

 

Abstract

In the result of Fe-Si grounding electrode characteristics investigation it was obtain, that the rate of anodic dissolution can be predicted by properties of thin film, formed preliminary. To determine the phase composition of the films is advisable to use the cathode recovery in hydrochloric acid electrolyte. Quantitative phase composition can be characterized by the potential recovery of the corresponding oxides. The share of the free surface can be calculated by tafelski factors anodic polarization dependences obtained by the method of pulse chronopotentiometry.

 

Keywords: ferrosilicon electrode; phase composition; part of free surface; rate of anodic dissolution; chronopotentiometric curves; the pressure sensor design.

 

Full text: [in elibrary.ru]

 

References

1. Roshchin V.E., Ryss M.A. i dr. Elektrometallurgiya stali i ferro-splavov [Electrometallurgy steel and ferroalloys]. Moscow, Metallurgiya Publ., 1974, 551 p.

2. Lipkin S.M., Lipkina T.V., Shishka V.G., Pozhidaeva S.A., Bolovinov E.V. Elektrokhimicheskii datchik dlya ustroistva lokal'nogo elektrokhimicheskogo ekspress-analiza [Electrochemical for the electrochemical device, the local Express-analysis]. Patent RF, no. 2008104530/22, 2008. 

3. Lipkina T.V., Pozhidaeva S.A., Kalaitanova N.E., Pyatibratova Yu.I., Kozlova T.A., Gavrilova M.A., Ibragimova V.V. [Investigation of possibilities to develop rapid methods kontol corrosion resistance ferrosilidovyh anode beds]. Aktual'nye problemy elektrokhimicheskoi tekhnologii. Sbornik statei molodykh uchenykh [Actual problems of electrochemical technology. Collected papers of young scientists]. Saratov, 2011, pp. 327 – 332.

4. Omurtag Y., Doruk M. Some investigations on the corrosion characteristics of Fe-Si alloys Corrosion ScienceVolume 10. Issue 4, 1970, P. 225 – 231.

5. Kuhn A.T. Anodic dissolution and oxygen evolution on binary and ternary iron-silicon alloys Electrochimica ActaVolume 28, Issue 4, April 1983, P. 515–527.

6. Mejía Gómeza J.A.,  Antonissenb J., Palacioa C.A. Effects of Si as alloying element on corrosion resistance of weathering steel Corrosion ScienceVolume 59, June 2012, P. 198–203.

7. Akademik. Khimicheskaya entsiklopediya [The academician. Chemical encyclopedia].  Available at:  http://dic.academic.ru (accessed on 17.02.2015).

8. Brainina Kh.Z., Bazarova E.V., Khodos M.Ya. Elektrokhimicheskie prevrashcheniya kisloroda na poverkhnosti oksidov [Electrochemical transformations of oxygen on a surface of oxides]. Elektrokhimiya, 1984, vol. 20, no. 5, pp. 613 - 619.

9. Lipkina T.V., Lipkin M.S., Gaidar A.I., Narochnaya V.M., Kucherenko E.I., Astakhov A.S., Kucherenko S.V., Pozhidaeva S.A., Shishka V.G. Prognozirovanie zashchitnoi sposobnosti oksidnykh plenok poverkhnostei nagreva teploenergeticheskogo oborudovaniya [Prediction of the protective ability of oxide films of the heating surfaces of thermal power equipment]. Kontrol' i diagnostika, 2014, no. 4, pp. 45 - 54.

10. Lipkina T.V., Yatsenko E.A., Lipkin V.M., Rapova N.V., Pozhidaeva S.A. Elektrokhimicheskaya korroziya ferritno-martensitnykh stalei v usloviyakh vysokotemperaturnogo para. Vliyanie doli svobodnoi poverkhnosti [Electrochemical corrosion the ferritno-martensitnykh staly in the conditions of high-temperature steam. Influence of a share of a free surface]. Izvestiya vuzov. Sev.-Kavk. region. Techn. nauki, 2013, no. 4, pp. 85 – 89. [In Russ.]