UNIV. NEWS. NORTH-CAUCAS. REG. TECHNICAL SCIENCES SERIES. 2022; 1: 60-65
http://dx.doi.org/10.17213/1560-3644-2022-1-60-65
OBTAINING AND PROPERTIES OF PERSPECTIVE COMPOSITE MATERIALS BASED ON CoFe2O4
Radjabov Asatullo M. – Graduate Student, Department «Ecology and Industrial Safety», natali.eroshenko.89@mail.ru
Shabelskaya Nina P. – Doctor of Technical Sciences, Associate Professor, Head of the Department «Ecology and Industrial Safety».
Taranushich Vitaliy A. – Doctor of Technical Sciences, Professor, Department «Chemical Technologies».
Sushkova Svetlana N. – Candidate of Biological Sciences, Leading Researcher of the Laboratory «Agrobiotechnologies for Improving Soil Fertility and Quality of Agricultural Products».
Ulyanova Vera A. – Student, Department «Chemical Technologies».
Abstract
A comparative characteristic of the properties of synthesized cobalt (II) ferrite and a composite material based on it is carried out. The search for a way to process waste to obtain new composite materials is an urgent task of chemical technology. The obtained samples were studied using X-ray phase analysis, Debye–Scherrer method, electron microscopy, BET. The catalytic properties of synthesized materials in the process of oxidative degradation of organic dye in the presence of hydrogen peroxide have been studied. It was found that the synthesized materials exhibit catalytic activity in this process, for the activated carbon/CoFe2O4 composite, the catalytic activity is higher: complete removal of the organic dye from the aqueous solution is achieved after 90 minutes from the start of the reaction.
Keywords: cobalt ferrite, organo-inorganic composite materials, waste, purification of aqueous solutions, catalytically active materials
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References
1. Bryndina L.V., Baklanova O.V. Restoration of soil from herbicidal pollution using biochar from sewage sludge and sawdust. Ecology and industry of Russia. 2021; 25(6): 32-37. (In Russ.).
2. Vedenyapina M.D., Kurmysheva A.Yu., Kryazhev Yu.G., Ershova V.A. Magnetic iron-containing carbon materials as sorbents for the extraction of pollutants from aqueous media (review). Chemistry of solid fuels. 2021; (5):15-37. (In Russ.).
3. Yang Z., Li Y., Zhang X., Cui X., He S., Liang H., Ding A. Sludge activated carbon-based CoFe2O4-SAC nanocomposites used as heterogeneous catalysts for degrading antibiotic norfloxacin through activating peroxymonosulfate. Chemical Engineering Journal. 2020; 384(123319).
4. Ma Q., Nengzi L.-C., Zhang X., Zhao Z., Cheng X. Enhanced activation of persulfate by AC@CoFe2O4 nanocomposites for effective removal of lomefloxacin. Separation and Purification Technology. 2020. (115978). DOI: 10.1016/j.seppur.2019.115978.
5. Zhao Y., Li J., Yin Z., Zhang X., Huang J., Cao L., Wang H. Interface-mediated local conduction at tubular interfaces in BiFeO3–CoFe2O4 nanocomposites. Journal of Alloys and Compounds. 2020; 823(153699).
6. Qian M., Cheng X., Sun T., Tian J., Isimjan T.T., Shi Z., Yang X. Synergistic catalytic effect of N-doped carbon embedded with CoFe-rich CoFe2O4 clusters as highly efficient catalyst towards oxygen reduction. Journal of Alloys and Compounds. 2020; 819(153015).
7. Zhu Z., Ma C., Yu K., Lu Z., Liu Z., Yan Y., Tang X., Huo P. Fabrication of CoFe2O4-modified and HNTs-supported g-C3N4 heterojunction photocatalysts for enhancing MBT degradation activity under visible light. Journal of Materials Science. 2020; 55(10): 4358-4371.
8. Sheoran A., Kaur J., Kaur P., Kumar V., Tikoo K.B., Agarwal J., Bansal S., Singhal S. Graphene based magnetic nanohybrids as promising catalysts for the green synthesis of β-amino alcohol derivatives. Journal of Molecular Structure. 2020;1204(127522).
9. Bagherzadeh S.B., Kazemeini M., Mahmoodi N.M. A study of the DR23 dye photocatalytic degradation utilizing a magnetic hybrid nanocomposite of MIL-53(Fe)/CoFe2O4: Facile synthesis and kinetic investigations. Journal of Molecular Liquids. 2020;301(112427).
10. Dos Santos J.M.N., Pereira C.R., Pinto L.A.A., Frantz T., Lima E.C., Foletto E.L., Dotto G.L. Synthesis of a novel CoFe2O4/chitosan magnetic composite for fast adsorption of indigotine blue dye. Carbohydrate Polymers. 2019; (217): 6-14.
11. Olusegun S.J., Freitas E.T.F., Lara L.R.S., Stumpf H.O., Mohallem N.D. Effect of drying process and calcination on the structural and magnetic properties of cobalt ferrite. Ceramics International. 2019; 45(7):8734-8743.
12. Petrenko D.S., Klushin V.A., Yatsenko A.N., Faddeev N.A., Ulyankina A.A. Composite materials based on bio-renewable poly-ethermaleinates. Izvestiya vuzov. North Caucasus region. Technical sciences=Bulletin of Higher Educational Institutions. North Caucasus Region. Technical Sciences. 2021; (4): 93-99. (In Russ.).
13. Khramenkova A.V., Ariskina D.N., Izvarin A.I. Synthesis of composite oxide materials by the method of unsteady electrolysis and investigation of their physico-chemical properties. Izvestiya vuzov. North Caucasus region. Technical sciences=Bulletin of Higher Educational Institutions. North Caucasus Region. Technical Sciences. 2019; (4): 112-116. (In Russ.)
14. Egorova M.A., Shabelskaya N.P., Radjabov A.M., Chernysheva G.M., Taranushich V.A., Zababurin V.M., Vyaltsev A.V., Ulyanova V.A. Obtaining and properties of ferrite and chromite of copper (II). Izvestiya vuzov. North Caucasus region. Technical sciences=Bulletin of Higher Educational Institutions. North Caucasus Region. Technical Sciences. 2021; (2): 69-74. (In Russ.).
15. Fan Y., Zhou Z., Feng Y., Zhou Y., Wen L., Shih K. Degradation mechanisms of ofloxacin and cefazolin using peroxymonosulfate activated by reduced graphene oxide-CoFe2O4 composites. Chemical Engineering Journal. 2020;38(123056).
16. Bigham A., Aghajanian A.H., Saudi A., Rafienia M. Hierarchical porous Mg2SiO4-CoFe2O4 nanomagnetic scaffold for bone cancer therapy and regeneration: Surface modification and in vitro studies. Materials Science and Engineering C. 2020; 109(110579).
17. Burachevskaya M.V., Minkina T.M., Sushkova S.N., Dmitriev P.A., Fedorenko A.G. A method for obtaining biochar from the husk of a salted strawberry in order to increase soil fertility. Database of Patent holder: Burachevskaya Marina Viktorovna. Certificate number: RU 2019621313. Patent Office: Russia, Application Number: 2019621053, Registered: 19.06.2019, Published: 18.07.20192019. Vol.: 3662 Kb. (In Russ.).