Scientific journal
Bulletin of Higher Educational Institutions
North Caucasus region

TECHNICAL SCIENCES


UNIV. NEWS. NORTH-CAUCAS. REG. TECHNICAL SCIENCES SERIES. 2022; 2: 56-60

 

http://dx.doi.org/10.17213/1560-3644-2022-2-56-60

 

SYNTHESIS OF FURAN MONOMERS FROM BIO-RENEWABLE RAW MATERIALS

Y.V. Kataria, V.P. Kashparova, D.V. Tokarev, V.A. Klushin

Kataria Yash V.Student, katariayash1603@gmail.com

Kashparova Vera P. – Candidate Technical Sciences, Associate Professor, Department «Chemical Technologies», kashparova2013@mail.ru

Tokarev Denis V. – Engineer of 1 category, Research Institute «Nanotechnology and New Materials», tokarev93rus@gmail.com

Klushin Victor A. – Candidate Technical Sciences, Associate Professor, Department «Chemical Technologies», victorxtf@yandex.ru

 

Abstract

Plant biomass is considered a major source of renewable carbon feedstock that is a viable alternative to crude oil and natural gas and provides compounds with low carbon footprint. The transition of the polymer industry to renewable plant-based raw materials will contribute to solving global environmental problems and ensure the sustainability and environmental safety of plastics production. This paper reports a simple and inexpensive synthesis of 5,5'-[oxybis(methylene)] bis[2-furaldehyde] (OBFA) and 5,5'-[oxybis(methylene)] bis-[2-furanmethanol] (OBFM) with an isolation yield of 95-97%, which are important biorenewable furan monomers that can become the basis for obtaining promising furan polyimines, polyesters and polyurethanes. The obtained compound was analyzed using nuclear magnetic resonance (NMR) spectroscopy and gaseous phase chromatography (GC).

 

Keywords: 5-HMF, OBFM, OBFA, biomass, monomers

 

Full text: [in elibrary.ru]

 

References

  1. Chernyshev V. M., Kravchenko O. A., Ananikov V. P. Conversion of plant biomass to furan derivatives and sustainable access to the new generation of polymers, functional materials and fuels. Russian Chemical Reviews. 2017; 86(5): 357 – 458. (In Russ.).
  2. Galkin K.I., Ananikov V.P. The Increasing Value of Biomass: Moving From C6 Carbohydrates to Multifunctionalized Building Blocks via 5‐(hydroxymethyl) furfural. ChemistryOpen. 2020; 9(11):1135 – 1148.
  3. Zhao X. et al. Biomass-based chemical looping technologies: the good, the bad and the future. Energy & Environmental Science. 2017; 10 (9): 1885 – 1910.
  4. Kucherov F.A. et al. Chemical transformations of biomass-derived C6-furanic platform chemicals for sustainable energy research, materials science, and synthetic building blocks. ACS sustainable chemistry & engineering. 2018; 6(7): 8064 – 8092.
  5. Bozell J.J., Petersen G.R. Technology development for the production of biobased products from biorefinery carbohydrates – the US Department of Energy’s “Top 10” revisited. Green chemistry. 2010; 12(4): 539 – 554.
  6. Krawielitzki S., Kläusli T.M. Modified hydrothermal carbonization process for producing biobased 5-HMF platform chemical. Industrial Biotechnology. 2015; 11(1): 6 – 8.
  7. Klushin V.A. et al. Technological aspects of fructose conversion to high-purity 5-hydroxymethylfurfural, a versatile platform chemical. Russian Journal of Organic Chemistry. 2016; 52(6): 783 – 787. (In Russ.).
  8. Hu L. et al. Catalytic advances in the production and application of biomass-derived 2, 5-dihydroxymethylfuran. ACS Catalysis. 2018; 8(4):2959 – 2980.
  9. Deng F., Amarasekara A.S. Catalytic upgrading of biomass derived furans. Industrial Crops and Products. 2021; (159): 113055.
  10. Opella S.J., Nelson D.J., Jardetzky O. Carbon magnetic resonance study of the conformational changes in carp muscle calcium binding parvalbumin. Journal of the American Chemical Society. 1974; 96(22):7157 – 7159.
  11. Timko J.M. et al. Host-guest complexation. 2. Structural units that control association constants between polyethers and tert-butylammonium salts. Journal of the American Chemical Society. 1977; 99(13): 4207 – 4219.